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Other corrections must be made to account for the proportion of throughout the biosphere (reservoir effects).Additional complications come from the burning of fossil fuels such as coal and oil, and from the above-ground nuclear tests done in the 1950s and 1960s.

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However, cosmic radiation constantly collides with atoms in the upper atmosphere.As a result it is always undergoing natural radioactive decay while the abundances of the other isotopes are unchanged.Carbon-14 is most abundant in atmospheric carbon dioxide because it is constantly being produced by collisions between nitrogen atoms and cosmic rays at the upper limits of the atmosphere.Isotopes participate in the same chemical reactions but often at differing rates.When isotopes are to be designated specifically, the chemical symbol is expanded to identify the mass (for example, C is not stable.The older a sample is, the less (the period of time after which half of a given sample will have decayed) is about 5,730 years, the oldest dates that can be reliably measured by this process date to around 50,000 years ago, although special preparation methods occasionally permit accurate analysis of older samples.

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